Final temperature real gas behaving ideally

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SUMMARY

The discussion focuses on calculating the final temperature of a gas mixture consisting of 1 mole of oxygen, 4 moles of nitrogen, and 3 moles of carbon dioxide, heated with 753 kJ in a well-insulated vessel. The relevant equation used is Eq. 3.48, which incorporates the specific heat capacities (α, β, γ) for each gas. The correct approach involves calculating the weighted averages of the α, β, and γ values based on the molar ratios of the gases. The initial temperature is a necessary parameter for determining the final temperature of the mixture.

PREREQUISITES
  • Understanding of ideal gas behavior and real gas corrections
  • Familiarity with thermodynamic principles, specifically heat transfer
  • Knowledge of specific heat capacities for gases (α, β, γ values)
  • Proficiency in using the equation Q/nR=α(T2-T1)+1/2β(T22-T12)+1/3γ(T23-T13)
NEXT STEPS
  • Calculate the weighted average of α, β, and γ for gas mixtures
  • Learn about the application of the first law of thermodynamics in gas mixtures
  • Study the concept of molar heat capacities and their significance in thermodynamics
  • Explore the implications of real gas behavior versus ideal gas assumptions
USEFUL FOR

Students and professionals in thermodynamics, chemical engineering, and physical chemistry who are involved in gas mixture calculations and heat transfer analysis.

Logan McEntire
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Homework Statement


Please consider a mixture of oxygen (1 mole), nitrogen (4 mole), and carbon dioxide (3 mole). The mixture was heated in a well - insulated vessel with 753 kJ.

Determine the final temperature if the mixture is composed of real gases behaving ideally as described by Eq. 3.48 truncated after the third term.
Q=753000 J
O2: α=3.626 β=-1.878 γ=7.055
N2: α=3.675 β=-1.208 γ=2.324
CO2: α=2.401 β=8.735 γ=-6.607
R=8.314 kJ/(kmol*K)

Homework Equations


EQ 3.48: Q/nR=α(T2-T1)+1/2β(T22-T12)+1/3γ(T23-T13)

The Attempt at a Solution


I know all the α,β,γ values for O2, N2, and CO2.
I know n=8 moles.
but I don't know the values of α, β, and γ for the mixture.
I thought of using a molar ratio of each element and multiplying that times each α, β, and γ then adding them all together but I wasn't sure if this was correct
 
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Yes, that's correct. Approximating the mixture as an ideal gas, the three components behave independently.
 
You will need to know the initial temperature.

Just to follow up on Chester's point,

##\Delta Q = \Delta U = (n_1C_{v1}+n_2C_{v2}+n_3C_{v3})\Delta T = (n_1+n_2+n_3)C_{vmix}\Delta T##

AM
 

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