Finding Expectation Value of Electric Dipole Moment Matrix Form

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SUMMARY

The discussion focuses on calculating the expectation value of the electric dipole moment matrix for a quantum system represented by the state |\Psi\rangle = c_1 |\psi_1\rangle + c_2 |\psi_2\rangle. The expectation value is derived using the integral \(\langle \mu \rangle = \int \Psi^* \mu \Psi d^3x\), leading to the conclusion that \(\langle \mu \rangle = \mu|c_1|^2 + \mu|c_2|^2\). The orthogonality of the eigenstates |\psi_1\rangle and |\psi_2\rangle ensures that the cross-terms vanish. The discussion also clarifies that the operator \(\mu\) should be treated as an operator defined by \(\mu = ex\), where \(e\) is the electron charge and \(x\) is the position operator.

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  • Quantum mechanics fundamentals, including eigenstates and operators
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  • Familiarity with orthogonality of quantum states
  • Basic knowledge of electric dipole moments and their significance
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Students and researchers in quantum mechanics, particularly those studying electric dipole moments and expectation values in quantum systems.

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Homework Statement


I we know the eigenstates of the system be [tex]|\psi_1\rangle[/tex] and [tex]|\psi_2\rangle[/tex]. Current state of the system is

[tex]|\Psi\rangle = c_1 |\psi_1\rangle + c_2 |\psi_2\rangle[/tex]

Try to find the expectation value of electric dipole moment [tex]\mu[/tex] (assume it is real) and write it in matrix form

2. The attempt at a solution
The expectation value of something is just the integral of that operator in given state, so

[tex]\langle \mu \rangle = \int \Psi^* \mu \Psi d^3x = \int (c_1^* \psi_1^* + c_2^* \psi_2^*)\mu(c_1 \psi_1 + c_2 \psi_2) = |c_1|^2 + |c_2|^2 + \int c_1^*c_2\psi_1^*\psi_2d^3x + \int c_1c_2^*\psi_1\psi_2^*d^3x[/tex]


The last two terms are zero because the eigenstates are orthogonal to each other, right?

so

[tex]\langle \mu \rangle = \mu|c_1|^2 + \mu|c_2|^2[/tex]


Is this correct? But what does it mean by writing it as matrix form?
 
Last edited:
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Isn't mu an operator defined by mu = ex, where e is the electron charge and x is the position operator. I think you treated mu as a number.
 

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