Finding Minimum Work to Compress Water

AI Thread Summary
To find the minimum work required to isothermally compress 1 kg of water from 1 bar and 120°C to one-third of its original volume, the phase of water is identified as superheated vapor. The specific volume at the initial state is used to determine the specific volume at the final state, which falls within the saturated liquid-vapor phase. The energy balance equation Q - W = U + KE + PE is discussed, with the assumption that kinetic and potential energy can be neglected. The conversation highlights the use of TdS equations for calculating heat transfer, suggesting that Q can be expressed as TΔS. Ultimately, the key focus is on determining the appropriate assumptions for energy balance in this context.
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Homework Statement


Find the minimum work to compress 1 kg of water isothermally from p1=1 bar, T1=120C to a volume that is 1/3 the original volume.

Homework Equations


Energy balance Q-W=U+KE+PE

The Attempt at a Solution


So first I found the phase of the water (p<psat for that temp so superheated vapor)
I found the properties (v,u,h,s) for that temperature and pressure in the superheated table.
I can use the specific volume at 1 to find the specific volume at 2 because mass stays constant (closed system) and it's just 1/3 v1. I used that specific volume to determine the state at 2 (in between vf and vg so it's in the saturated liquid vapor phase). I found the quality using tables so I can calculate u, h, s.

I'm mostly confused about the energy balance: I'm pretty sure I can neglect KE and PE. Is there a Q value though? When I went over this problem with the professor he hinted at using TdS equations (Gibbs?) for finding the heat. The Tds equation that I know is Tds=du+Pdv (which is similar to the energy balance since Pdv is the work and du is the the change in internal energy). Do I do W=du+Tds?

Or maybe it is okay to just assume no heat transfer and do W=U and then do m(u2-u1). I'm mostly confused about when you can assume things when doing energy balance.
 
Last edited:
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You know that the temperature is constant right, and for minimum work, Q = ∫TdS, so Q=TΔS. Just get the Δs from your tables and calculate Q.
 

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