Hi
@BillyT:
Thanks very much for the reference. I am a bit confused by your quote relative to what I read in the reference.
The quote above seems to be saying that the Einstein / Smoluchowski theory about fluctuations explains the blue sky. The following is a quote from the reference.
Einstein stated that "it is remarkable that our theory does not make direct use of the assumption of the discrete distribution of matter" . . .
There is no dispute, then, about what really causes the sky to be blue? Is it "really" scattering by molecules? Or, if you want to be more precise, scattering by electrons. Even more precise, scattering by bound electrons: free electrons would not give us a blue sky. The preposition "by" indicates an agent, and molecular scattering is the agent responsible for the sky's blueness.
This seems to contradict your quote's suggestion that molecules are
not responsible for the blue sky. Your quote seems to support the Einstein / Smoluchowski theory, and the references seems to say it's wrong. Or have I misinterpreted what you said? Or what the article says?
ADDED
Now that I have read the whole article, I get that any molecule of sufficiently small size, e.g. argon, would also make the sky blue, provided such molecules have no specific energy levels in its spectrum that would absorb blue light. So the reason that NO2 makes the sky blue is that NO2 makes up most (~80%) of the atmosphere. Since O2 makes up most of the remainder, I am curious. Does O2 also scatter light with smaller wavelengths like blue and violet? Regards, Buzz