The equality \Lambda(v)^{-1}=\Lambda(-v) can be derived from the Minkowski metric.
If your starting point isn't Minkowski space but instead Einstein's "postulates", and your goal is to "derive" the form of the Lorentz transformation, then the above equality should be viewed as a mathematical statement of (a weak version) of the first postulate. The first postulate isn't needed for anything else in the "derivation", but it's needed for this. Without this relationship, the gamma factor in the Lorentz transformation would have to be replaced by an arbitrary constant.
Note however that Einstein's postulates aren't well-defined enough to be taken as the starting point of a rigorous proof of anything. If you use this approach when teaching relativity, I think you should make that clear to your students. The "postulates" don't even say that spacetime is represented by \mathbb R^4, and they don't define what an inertial frame is. They don't explain what a "law of physics" is, and they mention "light" (which is something that can only be defined by a theory of electrodynamics) without making clear that "the speed of light" is only a reference to a particular set of curves in spacetime.
I'm not saying that it's a bad idea to use this approach. I'm just saying that it should be presented as what it really is: It's not a proof. It's just a way for us to find a mathematical model of spacetime that we can try to use in a new theory of physics. The model we end up with is of course Minkowski space. The actual postulates of SR (i.e. the statements that really define the theory) are the statements that describe the relationship between things we measure and things in Minkowski space.
Yeah, I know I'm nagging about this a lot. I do it because because it still irks me that none of the teachers who taught relativity at my university ever mentioned this, and that I didn't fully understand these things until years later. I'm thinking that if it took me a long time to figure this out, then there must be lots of other people who haven't figured it out yet (including many of those who teach relativity at universities).