Fuel/oxidizer preheating to a high temperature

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SUMMARY

Preheating hydrogen (H2) and oxygen (O2) to high temperatures significantly affects combustion efficiency and explosivity. When both gases are preheated to 1000 K, the resulting flame temperature is higher, but as temperatures increase to 3000 K, combustion efficiency decreases, with only half of the H2 and O2 reacting. At temperatures around 10000 K, combustion ceases entirely. Preheating widens the explosivity limits of the mixture, allowing for ignition with lower energy inputs, which can lead to spontaneous ignition under certain conditions.

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  • Familiarity with the concepts of explosivity limits
  • Basic principles of ignition and autoignition temperatures
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  • Research the effects of temperature on combustion efficiency in gaseous fuels
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Tera
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imagine you burn something, like H2 in O2. let's say you have a nice flame with a temperature T. for the sake of this discussion let's assume that T is 1000.

what happens if you preheat both H2 and O2 to 1000 first? is the resulting flame temperature higher? does the flame look the same? what happens if you preheat both H2 and O2 to 2x1000 or 5x1000 or 10x1000 ?
 
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Tera said:
what happens if you preheat both H2 and O2 to 1000 first? is the resulting flame temperature higher?

Yes.

Tera said:
what happens if you preheat both H2 and O2 to 2x1000 or 5x1000 or 10x1000 ?

The reaction will become less efficient. At around 3000 K only half of H2 and O2 will burn to water. At 10000 K nothig happens anymore.
 
The explosivity limits of a gaseous fuel-oxygen mixture are also wider if the mixture is pre-heated, and an electric spark of smaller energy is sufficient for ignition. If a ##H_2##/##O_2## mixture is heated close enough to the autoignition temperature, something like a single stray particle of ionizing radiation may be enough to trigger the explosion. That's the reason why the most sensitive explosive compounds may sometimes go off for no obvious reason.
 

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