Fundamental Thermodynamics Relation

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The formula dU = TdS - PdV relates changes in internal energy to entropy and volume. To compute partial derivatives like ∂U/∂P or ∂P/∂T, it's essential to specify which variables are held constant during the differentiation process. This clarity is crucial for accurately interpreting thermodynamic relationships. Understanding the context of each variable allows for proper application of Maxwell's relations and other thermodynamic identities. Properly addressing these conditions will lead to the correct calculations of the desired partial derivatives.
Silviu
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Hello! I am a bit confused by the formula ##dU = TdS - PdV##. If I want to compute for example ##\frac{\partial U}{\partial V}## I obtain ##-P##, but how should I proceed to obtain, for example ##\frac{\partial U}{\partial P}## or ##\frac{\partial P}{\partial T}## which are not obvious from the equation? Thank you!
 
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For those partial derivatives you mention, you need to specify what is being held constant.
 
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