Gas in tank exposed to a vacuum

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The discussion centers on a thermodynamics problem involving a tank divided into a vacuum and argon gas at high pressure. When the divider bursts, the gas expands into the vacuum, prompting questions about the new temperature and pressure of the gas. Participants emphasize the importance of the ideal gas law and the relationships between pressure, volume, and temperature, while also considering the internal energy changes during the expansion. It is noted that assuming no temperature change requires justification, and the first law of thermodynamics is suggested as a means to analyze the situation. Ultimately, the problem illustrates key concepts in gas behavior during free expansion.
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Homework Statement


A tank is equally divided into two equal halves, one a vacuum and one filled with argon gas at 298K and 700 bar. The divider bursts and the gas equally disperses throughout the tank. What is the new T and P of the gas assuming argon is an ideal gas?


Homework Equations


PV=nRT P1V1/T1=P2V2/T2


The Attempt at a Solution


I assumed there was no temperature change which I am unsure of but using that logic, P=350 bar and T=298K
 
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Begin with the definiton of an ideal gas. Hint: it's more than just pV = nRT.
What can you say about the dependence of U, internal energy, as a function of p,V and/or T?
Then go with the first law and show that you get the same results whether the free expansion is adiabatic or isothermal or anything inbetween.
 
GZunich said:

Homework Statement


A tank is equally divided into two equal halves, one a vacuum and one filled with argon gas at 298K and 700 bar. The divider bursts and the gas equally disperses throughout the tank. What is the new T and P of the gas assuming argon is an ideal gas?


Homework Equations


PV=nRT P1V1/T1=P2V2/T2


The Attempt at a Solution


I assumed there was no temperature change which I am unsure of but using that logic, P=350 bar and T=298K

You can't make that assumption unless you can prove it.

Begin with the definiton of an ideal gas. Hint: it's more than just pV = nRT.

What can you say about the dependence of U, internal energy, as a function of p,V and/or T?

Then go with the first law and determine if you get the same results whether the free expansion is adiabatic or isothermal or anything inbetween.
 

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