Is Ground Level Ozone the Same as Smog?

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Ground level ozone is not just another term for smog; it is a key component of photochemical smog, formed from pollutants like unburned hydrocarbons emitted by vehicles. The production of ground level ozone involves a series of chemical reactions. Initially, nitrogen and oxygen combine in engine cylinders to produce nitrogen monoxide (NO). This NO then reacts with oxygen in the atmosphere to form nitrogen dioxide (NO2), which further reacts with water vapor to create nitric acid (HNO3). Sunlight plays a crucial role by breaking down NO2 into NO and free oxygen, which subsequently reacts with molecular oxygen (O2) to form ozone (O3). The kinetics of ozone production are influenced by temperature, as higher temperatures increase the reaction rates due to more energetic particles. For further information on the environmental effects of ground-level ozone, a resource from the EPA is available at http://www.epa.gov/ttn/oarpg/naaqsfin/o3health.html.
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Hi, I have to do a report on ground level ozone and was just wondering if that is just another word for smog. Also, I need help in answering the following questions:

b) What are mechanisms of the reactions that lead to the production of ground level ozone?

c) What is the connection between the production of ozone and kinectics?

Any help is greatly appreciated. If any information that you write here is taken from another website, could you please leave the link as well so I could investigate further. Thanks.
 
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adeel said:
Hi, I have to do a report on ground level ozone and was just wondering if that is just another word for smog. Also, I need help in answering the following questions:

b) What are mechanisms of the reactions that lead to the production of ground level ozone?

c) What is the connection between the production of ozone and kinectics?

Any help is greatly appreciated. If any information that you write here is taken from another website, could you please leave the link as well so I could investigate further. Thanks.

Smog is a colloid, or more specifically, a solid and liquid dispersed in a gas.

Ground level ozone is a pollutant that oxidizes compounds which then mixes with air, water vapor, and dust to form photochemical smog. This ozone is produced from unburned hydrocarbons from things such as internal combustion engines and occurs in several steps.

1. Sometimes nitrogen combines with oxygen in the engine's cylinders, producing the free radical NO: N2 + O2 --> 2NO

2. When these free radicals reach the air, it again reacts with oxygen to produce NO2 radicals that react with water vapor to form HNO3:
a. 2NO + O2 -->2NO2
b. 3NO2 + H2O --> NO + 2HNO3

3. Sunlight reacts with the NO formed in the second reaction that splits it up into nitrogen and oxygen: NO2 --sunlight--> NO + O

4. The free oxygen reacts with O2 atoms to form ozone: O + O2 --> O3

I got this from the Modern Chemistry book by Holt, Rinehart, and Winston.
Im not quite sure about the kinetics, but maybe it is related to temperature (the higher the temperature the faster the rate due to more energetic particles).

This link shows the environmental effects of ground-level ozone:
http://www.epa.gov/ttn/oarpg/naaqsfin/o3health.html
 
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