Electron Excitation and Photon Emission: Understanding the Ground State

In summary: As long as the system goes from a higher energy state to a lower energy state and follows the selection rule, a photon can be emitted regardless of whether it reaches the ground state or not. In summary, an electron can absorb a photon and exist in an excited state, and then emit a photon of higher frequency than it absorbed as it falls to a lower energy state, even if it does not reach the ground state. This is possible as long as the system follows the selection rule.
  • #1
MathewsMD
433
7
Just curious: if an electron absorbs a photon of energy, it is in an excited state. The electron may go to a lower energy state (but NOT the ground state). Can a photon (of higher wavelength than absorbed) be emitted still?

I don't quite see the importance of the electron having to go to the ground state in this case...
 
Physics news on Phys.org
  • #2
Do you mean a longer wavelength, or a higher frequency? A "higher wavelength" doesn't make sense.

In any case, an electron can exist above the ground state, absorb a photon, and then fall to a lower state than what it was occupying emitting a photon of higher frequency than what it absorbed in the process.
 
  • #3
Drakkith said:
Do you mean a longer wavelength, or a higher frequency? A "higher wavelength" doesn't make sense.

In any case, an electron can exist above the ground state, absorb a photon, and then fall to a lower state than what it was occupying emitting a photon of higher frequency than what it absorbed in the process.

Isn't a higher wavelength proportional to lower energy? How would it emit a higher energy photon (i.e. higher frequency) than what it absorbed?

So to confirm, a photon can still be emitted despite the electron not decaying to its ground state, just any state lower than its excited state, correct?
 
  • #4
A photon can be emitted if the system goes from a higher energy state to a lower energy state (not necessarily the ground state), and if it abides by the selection rule.

Example: the Balmer lines in H atom.

Zz.
 
Last edited:
  • #5
MathewsMD said:
Isn't a higher wavelength proportional to lower energy? How would it emit a higher energy photon (i.e. higher frequency) than what it absorbed?

The extra energy required to emit a photon of higher frequency than the electron absorbs comes from the extra energy it already had by being in a state above the ground state.

So to confirm, a photon can still be emitted despite the electron not decaying to its ground state, just any state lower than its excited state, correct?

Absolutely.
 

Related to Electron Excitation and Photon Emission: Understanding the Ground State

What is the ground state?

The ground state refers to the lowest energy state that an atom or molecule can be in. In this state, all of the electrons are in their lowest possible energy levels.

How is the ground state determined?

The ground state is determined by the electron configuration of an atom or molecule. This configuration is based on the number of electrons and their arrangement in the various energy levels.

Can an atom or molecule have multiple ground states?

No, an atom or molecule can only have one ground state. This is because the ground state is the lowest energy state possible, and there can only be one lowest energy state.

What is the significance of the ground state?

The ground state is significant because it is the starting point for understanding the behavior and properties of atoms and molecules. It also helps in predicting the chemical reactivity and stability of a substance.

Can the ground state be changed?

Yes, the ground state can be changed by providing energy to the atom or molecule. This causes the electrons to move to higher energy levels, resulting in a new ground state.

Similar threads

  • Other Physics Topics
Replies
16
Views
1K
  • Other Physics Topics
Replies
16
Views
4K
Replies
2
Views
717
  • Other Physics Topics
2
Replies
56
Views
4K
  • Quantum Physics
Replies
3
Views
2K
  • Atomic and Condensed Matter
Replies
6
Views
1K
Replies
6
Views
2K
Replies
1
Views
985
  • Atomic and Condensed Matter
Replies
23
Views
2K
  • Other Physics Topics
Replies
4
Views
1K
Back
Top