@Born2beWire: It does. With the spheres ungrounded and isolated, the charges will separate with the opposite charges attracted towards the charged rod and the like charges moving away. The result is as you describe with the charges bunching up on opposite surfaces. A ground is a charge sink/source and it acts like a conductor. Thus, the charges can move freely into and out of the ground in response to an induced voltage. This means that the like charges that moved to the opposite surface can now be repelled into the ground. The result is that now the spheres (assuming they remain in contact) now have a net charge (because you have driven the like charges off of the spheres down the ground connection)...
Ah yes but my question (as EHT has kindly replied) was whether there would be a difference where I put my grounding wire. If I use the negatively-charged rod to the induce the charges on the spheres (positive->nearer and negative->further), it seems unintuitive that the same effect would occur (i.e. the dissipation of the negative charges on the further sphere to ground) even if i put the ground wire right on the surface where the positive charges are(nearer sphere). But I guess since your reply makes no mention of where you place the grounding wire that you also think that location is irrelevant?