Hamiltonians, do they need to be positive definite?

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Discussion Overview

The discussion revolves around the properties of Hamiltonians in quantum mechanics and their requirements regarding positive definiteness and boundedness from below. Participants explore whether these properties are necessary in both non-relativistic and relativistic contexts, as well as the implications of these requirements on physical systems.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions whether Hamiltonians need to be positive definite, seeking clarification on its necessity in quantum mechanics and relativity.
  • Another participant asserts that Hamiltonians do not need to be positive definite, citing the example of the Hydrogen atom's ground state energy being negative.
  • A third participant agrees that while Hamiltonians do not need to be positive definite, they typically must be bounded from below to ensure the existence of a ground state.
  • It is mentioned that a Hamiltonian can be adjusted by adding a constant to shift the energy levels, which can make it positive definite without altering the physics.
  • One participant introduces the idea that requiring supersymmetry could lead to positive energy outcomes for Hamiltonians.
  • A participant raises a question about the necessity of Hamiltonians being bounded from below, suggesting that this requirement may stem from a desire to avoid infinite energy sources, but seeks a more precise mathematical justification.
  • Another participant argues that there is no mathematical constraint enforcing boundedness from below, framing it as a physical requirement, and provides an example of a potential that is not bounded from below.

Areas of Agreement / Disagreement

Participants express differing views on the necessity of positive definiteness and the boundedness of Hamiltonians. While some agree on the importance of being bounded from below, the discussion remains unresolved regarding the implications of these properties in both quantum and relativistic frameworks.

Contextual Notes

Participants note that the requirement for Hamiltonians to be bounded from below is not strictly a mathematical necessity but rather a physical one, with examples provided to illustrate the consequences of unbounded Hamiltonians.

mtak0114
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Hi
(I'm not sure where this question belongs)
I had a general question about hamiltonians, do they need to be positive definite?
is this required in QM, or is this a relativistic requirement?

cheers

M
 
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Hamiltonians do not need to be positive definite. The eigenvalues of the Hamiltonian are the energies. In standard notation, the energy of the ground state of the Hydrogen atom is about -13.6 eV, i.e. negative => one example of a negative eigenvalue => my statement.

I'm not completely sure that I understood your question, hence the explanation.
 


Timo is correct. However, you typically demand that a Hamiltonian is bounded from below. Otherwise there is no ground state.

Once you have a such a Hamiltonian, you could just trivially add a constant to the Hamiltonian (which doesn't change the physics) such that the lowest energy state (the ground state) has zero energy. It's often the convention to label a state that is not the ground state as zero energy (such as for the mentioned hydrogen atom). However, these Hamiltonians can always be chosen to be positive definite by a constant energy shift. This is why you may have seen some sort of general argument for something that assumes a positive definite Hamiltonian (assuming this is why you asked the question).
 


This might be a little irrelevant, but I want to mention that if one requires supersymmetry then it is true that the energy will always be positive.
 


thanks for the replies

this agrees with what I was thinking
but from a relativistic perspective this
wouldn't the hamiltonian need to be positive definite
as the 4-momentum operator must have time like eigenvalues?
i.e. timelike four-momenta

as another question
what is the reason for a hamiltonian to be bounded from below?
I understand that this is required if one would like to avoid having an infinite energy source.
But is there a precise mathematical reason or is this simply a constraint that we as physicists impose?

thanks again

Mark
 
Last edited:


mtak0114 said:
as another question
what is the reason for a hamiltonian to be bounded from below?
I understand that this is required if one would like to avoid having an infinite energy source.
But is there a precise mathematical reason or is this simply a constraint that we as physicists impose?

thanks again

Mark

I don't think that there are any mathematical constraint that restricts the Hamiltonian to be bounded from below, this is a physical requirement. Take for example a potential of the form [tex]V(x) = x^3[/tex], then the Hamiltonian will not be bounded from below (and there is no mathematical reason for this not to be allowed)! I think that when this is solved, the particle will go to infinity in finite time, and therefore not so physical.
 

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