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Harmonic Potentials and energy state populations

  1. Apr 16, 2009 #1
    Hi All - Let's say I have a potential energy surface with two minima, one higher than the other. We will label the higher minima B and the lower minima A. Each potential well can be approximated as a harmonic potential with force constants kA and kB for wells A and B respectively. How small must kB be in terms of kA in order for that state (higher energy) to be the more likely state at temperature T?
     
  2. jcsd
  3. Apr 16, 2009 #2
    Sry to bump my own thread. I'm really dying on this one here, any help is much appreciated.
     
  4. Apr 17, 2009 #3
    Is anyone out there? I've yet to get a response to anything I've posted on this site :-(
     
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