The stopping voltage in a photoelectric cell, set at 2.00V, indicates the potential needed to halt the most energetic emitted electrons. When no voltage is applied, it does not mean the electrons have zero kinetic energy; rather, they possess initial kinetic energy from the incoming photons. The confusion arises from equating zero applied voltage with zero kinetic energy, which is incorrect. The maximum speed of the electrons can be determined using the stopping voltage to calculate their kinetic energy. Understanding that electrons are emitted with kinetic energy is crucial for solving the problem accurately.