How are angles in molecules calculated?

AI Thread Summary
The discussion centers on understanding bond angles in molecules, specifically focusing on methane (CH4) and its tetrahedral geometry. The bond angle between hydrogen atoms in methane is 109.5°, which is explained by the Valence Shell Electron Pair Repulsion (VSEPR) theory. This theory posits that electron pairs around a central atom will arrange themselves to minimize repulsion, resulting in the tetrahedral shape for molecules with four bond pairs and no lone pairs. Participants express confusion about the calculation of these angles and seek clarification on how the specific angle of 109.5° is derived. A link to a Khan Academy resource is shared, which provides a proof for the tetrahedral bond angle, helping to clarify the concept for some participants.
IDK10
Messages
67
Reaction score
3
I understand how angles are calculated in compounds where an atom is bonded to 2, 3, 5, and 6 bonds (bond pair + lone pair). But how do they work out the angle of a compound where an atom has 4 bonds (i.e. methane), in this case the carbon atom, has a H-C-H angle of 109.5°
 
Chemistry news on Phys.org
Please elaborate, I fail to see how it is different.
 
Borek said:
Please elaborate, I fail to see how it is different.
In methane and any other compound containing an atoms which only has 4 bond pairs and 0 lone pairs of electrons. The bond between the three atoms (in the case of methane, it is the H-C-H bond angle), it is 109.5°, I was wondering how they worked that out.
 
And how they worked out the value for water molecule, or for any other molecule with any number of bonds and/or lone pairs?

I don't see why you say you know how to deal with other molecules, but you think this particular molecule is different.
 
Borek said:
And how they worked out the value for water molecule, or for any other molecule with any number of bonds and/or lone pairs?

I don't see why you say you know how to deal with other molecules, but you think this particular molecule is different.
I'm not saying that, I'm asking how they first got the bond angles for an atom with 4 bond pairs, I'm just giving methane as an example.
 
Sorry, I still fail to see where the problem is.

You know how to calculate angle for atom bonded to two other atoms. Can you explain how it is done?

You know how to calculate angle for atom bonded to three other atoms. Can you explain how it is done?
 
Comeback City said:
The C-H bonds want to be as far apart from each other as possible, as is stated by VSEPR, so they spread out to that 109.5 °. If you are asking why it is 109.5, then

We don't know what he is asking. That's what I am trying to find out.
 
Borek said:
We don't know what he is asking. That's what I am trying to find out.
Good call :cool:
 
Back
Top