How can C4 be detonated by heat or shock, only by electricity?

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Superposed_Cat
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I was thinking about electroactive polymers, and wondering if any exist that are immune to high temperatures, and although explosive decomposition is a completely different subject, it got me thinking about c4.

Chemically speaking, what gives a compound such as c4 the ability to not detonate via the thermal energy or kinetic but can be detonated by electricity?

Almost all explosives I know off will detonate with 2/3, what makes c4 so different?

Any insight appreciated.
 
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