To center boundary conditions (BC) at a point in a circle within the complex plane, it's suggested to introduce a geometric entity at the circle's center during the modeling phase. If the circle is already drawn, users can edit it by accessing the "draw" section and reassembling it with new features, such as adding a point at the center. For simpler solutions, looking for internal BC options in the software is recommended. If internal BCs are unavailable, replacing the circle with a donut shape that has a very small internal radius can allow for the application of regular BCs near the center. Additionally, there is interest in learning how to input BCs by specifying coefficients, particularly in scenarios like setting zero mass transfer in a 1D system, indicating a need for clearer guidance on this topic.