Experiencing mild pain upon contact with sugary substances may indicate underlying dental issues, potentially cavities, even if they are not yet visible on x-rays. Teeth consist of hard enamel and porous dentin, with sensitive nerves located in the pulp. Sugar itself is a molecular compound, not ionic, but its interaction with bacteria can lead to acid production that damages enamel, making teeth more sensitive. If gums are inflamed, this can also expose sensitive areas of the teeth. It's advisable to consult a dentist for an x-ray to check for cavities, as untreated issues can lead to more severe problems like root canals. Additionally, using fluoride rinses or products designed for sensitive teeth may help strengthen enamel.