How Does Blue Tack Adhere to Smooth Surfaces?

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Discussion Overview

The discussion revolves around the mechanisms by which blue tack adheres to smooth surfaces, particularly focusing on the forces involved in its stickiness, the role of hydrocarbon polymers, and the nature of adhesion without chemical reactions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions whether electromagnetic forces are responsible for the adhesion of blue tack to smooth surfaces.
  • Another participant suggests that the stickiness is due to long-chain hydrocarbon polymers, which form physical bonds with surfaces.
  • A different participant challenges the explanation of stickiness, asking for clarification on what it means for a substance to be sticky and how hydrocarbon polymers can be adhesive despite being non-polar.
  • There is a proposal that the molecular structure of blue tack may resemble either that of metal or rubber, raising questions about its elastic properties and the forces involved in its adhesion.
  • One participant references hydrogen bonding phenomena, suggesting that there may be more complex interactions at play than previously discussed.

Areas of Agreement / Disagreement

Participants express differing views on the mechanisms of adhesion, with no consensus reached regarding the role of hydrogen bonding or the nature of the polymers involved. The discussion remains unresolved with multiple competing explanations presented.

Contextual Notes

Participants express uncertainty regarding the adhesive properties of hydrocarbon polymers and the implications of their non-polar nature. The discussion also highlights unresolved questions about the molecular structure and behavior of blue tack.

sniffer
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suppose we have a very smooth and hard surface such as mirror, and we stick a blue tack on it.

there is no chemical reaction. what force keeps it stuck?

is it electromagnetic?
 
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It's not electromagnetic as such, although there are certainly electromagnetic forces which play a part in the bonding within the substance.

It's just sticky! Long-chain hydrocarbon polymers often form these gooey, sticky substances. Turning them into a usable product is just a case of getting the right balance of tackiness, without being too sticky.


http://www.madsci.org/posts/archives/Jan2003/1043271591.Ph.r.html
 
A good reference Brewnog, but for my money "becasue it's sticky" isn't really an answer. What does it mean for something to be sticky?

I found the answer (or at least, the author's belief) in your link:

"...Hydrocarbon polymers is the adhesive component in Blu-Tack. Polymers tend
to be pretty sticky; they are long chained hydrocarbons that have lots of
hydrogen on the surface that tend to form physical bonds with anything
that they come in contact with
..."
 
Hi there,
I'm also very interested in the mechanism of blu-tack.
I don't really understand why hydrocarbon polymers are adhesive. From my chemistry knowledge, hydrocarbon polymers are supposed to be non-polar, leave alone forming hydrogen bonds. Their nature should be like oil - slippery instead of sticky.
However, let's assume it is a long carbon chain with a lot of OH groups attached. How do you explain then, that blu-tack also sticks to smooth non-polar substances? No hydrogen bonds are supposed to be formed. I am still very confused.
Moreover, blu-tack has the property of being elastic, yet capable of being molded. Is its molecular structure like that of metal, which recoils by electrostatic force, or is it like a rubber band, which recoils due to thermo-energy?

source: http://en.wikipedia.org/wiki/Natural_rubber#Properties
In most elastic materials, such as metals used in springs, the elastic behavior is caused by bond distortions. When force is applied, bond lengths deviate from the (minimum energy) equilibrium and strain energy is stored electrostatically. Rubber is often assumed to behave in the same way, but it turns out this is a poor description. Rubber is a curious material because, unlike metals, strain energy is stored thermally.
 

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