How many peaks will there be in an NMR spectrum for Malic Acid?

AI Thread Summary
The NMR spectrum of Malic Acid, HOOC CH2 CH(OH) COOH, will show peaks corresponding to different hydrogen environments. There are four distinct environments: one for the two identical -COOH groups, one for the -OH hydrogen, one for the hydrogen on the carbon bonded to -OH, and one for the two hydrogens on the remaining carbon. The question of whether to count doublets and triplets as one peak or multiple peaks is raised, indicating a need for clarification on peak counting conventions. The total number of peaks could be four or five, depending on the identity of the carboxylic acid groups. Understanding these environments is crucial for accurate NMR interpretation.
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1. Homework Statement

How many peaks will there be in the NMR spectrum of Malic Acid, HOOC CH2 CH(OH) COOH, WITHOUT D2O as the solvent (i.e. Hydrogens in Hydroxyl groups WILL have corresponding peaks)?


3. The Attempt at a Solution

I thought the two -COOH groups will be identical Hydrogen environments, so there would only be one peak for both. There will be one environment with the single H bonded to the Carbon that is also bonded to the OH; one environment with the single H in the -OH bonded to that same Carbon; and one environment with the two H's bonded to the remaining Carbon. A total of 4 peaks without D2O (or 5 if the Carboxylic acid groups are not identical)?
 
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Do you count doublets as one peak or two? Triplets as one peak or three?
 
Triplets as one, doublets as one
 
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