Electricity and Magnetism by Francis Weston Sears:
Any device in which a reversible transformation between electrical energy and some other form of energy can take place, is called a seat of electromotive force. The magnitude of the electromotive force of a seat may be defined quantitatively as the energy converted from electrical to nonelectrical form or vice versa (exclusive of energy converted irreversibly to heat) per unit of charge passing across a section through the seat. More briefly, electromotive force may be defined as the work per unit charge.
Since electromotive force is work per unit charge, the unit of emf in the mks system is one joule per coulomb. This is the same as the unit of potential and has been abbreviated to one volt. Hence emf's can be expressed in volts. It should be noted, however, that, although emf and potential are expressible in the same unit, they relate to different concepts.
..., the emf of the common automobile storage battery is about 6 volts or 6 joules /coulomb. This means the for every coulomb pasing across a section through the batters (or across any section of a circuit to which the battery is connected) 6 joules of chemical energy are converted to electrical form if the battery is discharging, or 6 joules of chemical energy are developed at the expense of electrical energy if the battery is being charged.
Chet