How to build a circuit for an electrochemical to extract different metals

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SUMMARY

This discussion focuses on constructing an electrochemical cell for the selective recovery of metals such as gold, silver, and copper from wastewater using a High Surface Area Cathode made of carbon. The proposed method involves applying incremental voltages, starting from 0.5V and increasing to 2V, to selectively extract metals based on their electrochemical potentials. Participants emphasize the importance of understanding the electrochemical series to determine the appropriate voltages for each metal recovery process. Chemistry knowledge is crucial for successfully implementing this project.

PREREQUISITES
  • Understanding of electrochemical cells and their components
  • Knowledge of electrochemical series and metal potentials
  • Familiarity with High Surface Area Cathodes, specifically carbon
  • Basic principles of voltage application in electrochemical reactions
NEXT STEPS
  • Research the electrochemical potentials of gold, silver, and copper
  • Learn about the construction and operation of electrochemical cells
  • Explore methods for optimizing High Surface Area Cathodes
  • Investigate voltage application techniques for selective metal recovery
USEFUL FOR

This discussion is beneficial for chemists, environmental engineers, and hobbyists interested in electrochemical processes for metal recovery from wastewater.

gedfire
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Hello All,

I am trying to build what is essentially an electrochemical cell which I will use to filter waste water and try to recover gold silver and copper among other metals on a High Surface Area Cathode like Carbon.I want this electronic filter to be selective about the metals recovered based on their positions in the electrochemical series. How could I go about that? I was thinking I could start at low voltages first eg: 0.5v then the next cell would have maybe 0.9 v and the next 1.3 v then 2v in that order.

Any suggestions as to the circuit needed parts operating principles? is it possible?

Gary
 
Last edited:
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Yes you can do it selectively based on voltage. What voltage? You need to look up the electrochemical potential for each chemical reaction you need.

Then separate lowest voltage constituent first, then pass the solution to the next highest voltage, and so on.

So you'll have to do a fair bit of chemistry homework, not electrical.
 

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