How to Calculate the Madelung Constant for an Octahedral Arrangement?

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Homework Statement


Calculate the Madelung constant for an octahedral arrangement of doubly charged anions about a doubly charged cation. Use r0 for the anion−cation distance. (Hint: Remember that the Madelung constant considers the sum of Coulomb interactions over all atom/ion pairs).


Homework Equations



Possibly helpful Equations
EA=-(Mke2)/r0

α=2M/((n1+n2)|Z1Z2|)

EA=-(ke2α(n1+n2(|Z1Z2)/2r0

The Attempt at a Solution



So we have a theoretical bond pair X+2Y-2 with a coordination number of 6.

I believe the next step should be to calculate EA, but I fail to see how to do that without α.
 
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Your Madelung equation doesn't seem familiar to me, what textbook are you using?
 
Here is a screenshot of my professors notes I took these equations from.

Notes_zps8f083b95.jpg


This is our book:

https://www.amazon.com/dp/0521651514/?tag=pfamazon01-20

What equations would you have used?
 
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None of these. Madelung constant is calculated just by summing electrostatic interactions between ions.
 
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