So the easiest way to do this is by looking at the particles involved, and knowing how different particles interact. For example, if you see a neutrino, you know immediately that it was a weak decay, eg:
π+ -> π0 + e+ + ve
Because neutrinos only interact with the weak force.
Similarly, you know that this
Z0 -> e+ + e-
must be weak, because Z0 is neutral and non-composite, so no EM, and electrons don't feel the strong force.
However,
π0 ->e+ + e-
May be EM or weak, but strong is forbidden (same as above), however weak is less probable in this instance, because of the timescales of the reactions - τEM=10^-16s, τweak=10^-10s. This is true in general. If it can go by strong, it will mostly go by strong, and so on.
Anything that involves a γ must be a EM interaction, because γ feel the EM interaction.
Anything with a flavour change must be from a weak interaction, because it is the weak interaction that changes flavour, for example
D+-> K- + π+ + π-
(The easiest way to see that is to write out the quarks).
What about something like
p + \overline{p} \rightarrow \pi^+ + \pi^-?
In this case, it is not forbidden by the strong force, therefore most of the time it will happen by the strong force.
By the way, this is from something called the Totalitarian Priniciple that states that any decay that is not forbidden must occur. In this way, you can uncover new conservation rules - if a reaction doesn't happen, you have to figure out why.