How to write Stoichiometric ratio of a reaction?

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The discussion centers on determining the stoichiometric ratio of the reaction between H2N(CH2)3NH2 (a diamine) and HOOCCH2(C6H4)CH2COOH (a dicarboxylic acid). Participants concluded that the stoichiometric ratio can vary based on the reaction conditions, with common ratios being 1:1, 1:2, or 2:1, depending on the products formed, such as salts or polyamides. The consensus is that the average stoichiometric ratio for the reaction is typically 1:1, particularly when considering the formation of polyamides. The discussion highlights the importance of understanding the specific reaction context rather than merely focusing on the chemical equation.

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wirefree
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Seasons' Greetings.

I have been asked to express the reaction of H2N(CH2)3NH2 with HOOCCH2(C6H4)CH2COOH in a stoichiometric ratio.

Would appreciate some guidance, not with the equation in particular, but the semantics of it.wirefree
 
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Can you see what functionality there is in your starting materials that will undergo the reaction?
 
Basically they ask to write reaction equation (that's where the sjb hint comes handy) and to write ratio of the coefficients. For example stoichiometric ratio of KOH to H2SO4 is 2:1 (assuming full neutralization is the reaction that is the most obvious one).
 
I'm half-way there:

For the two compounds, the reaction produces 2 molecules of H2O and NH(CH2)3NHCOCH2(C6H4)CH2CO

Just whose ratio is needed?

Thank you for your guidance,
wirefree
 
Ratio of reacting compounds.
 
Er, the products of that reaction can themselves undergo the same reaction so there are many products, a mixture of similar things, I don't remember whether this is a common polymer (or rather "copolymer"), obviously the average ratio of the two things in them is 1:1 or close. Seems more a question of pedantic terminology than substance.
 
Last edited:
I tried 1:1 but it got marked in the red.

What else can I try?
 
Sorry, this is more about a mind reading (what the question author had on mind) than about chemistry.

You have a diamine and a dicarboxylic acid. They can react producing a salt - and they will react 1:1, or 1:2, or 2:1, depending on the ratio of substances mixed. They can react producing amide - again, several ratios are possible, but in the case of long chain being produced (polyamide) stoichiometric ratio is 1:1.

I don't see any better answer than 1:1 and I have no idea what they expect.
 
Many thanks to all who attempted to address my concerns (& mind-reading the author).

For your reference, the question is part of edX.org's MITx: 3.091x Introduction to Solid State Chemistry course.wirefree
 

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