Hydrogen Emission Spectrum, Electrons, and Quantized Energy

In summary, the hydrogen emission spectrum experiment showed that electrons only emit certain wavelengths of light, which led to the conclusion that they emit light when they relax and absorb light when they get excited. This proves that the energy for electrons is quantized because they can only absorb and release energy in specific amounts. This results in a pattern of possible energy values for electrons, which can be shifted from their ground state to their excited state by absorbing or emitting photons with specific allowed frequencies. Without this quantization, a continuous spectrum would be expected instead of the observed discrete lines.
  • #1
Chrizappin
1
0
I understand that the result of the hydrogen emission spectrum experiment was that only certain wavelengths of light were emitted and that led to the conclusion that electrons emit light when they relax and that they absorb light when they get excited. How does that prove that the energy for electrons are quantized?
 
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  • #2
if an electron in a hydrogen atom can only absorb and release energy in discrete amounts, then whenever you measure the energy of an electron, it can only have one of a specific set of values (not counting an arbitrary zero point).

In short, if the electron has some energy E0, and it's changes in energy only come from photons with specific allowed frequencies, then the possible values of the energy of that electron will be E0 plus or minus the energies of the photons absorbed and emitted, respectively. We can set E0 to be any number we like, but that won't change the pattern of possible energy values that electron can have, only what counts as "zero".
 
  • #3
What kind of a spectra would you expect to get from an electron if its energy were not quantized? Single lines, or a continuous spectrum?
 
  • #4
We would have gotten
A continuous spectrum
If that's the case
The energy of an electron is quantised
Because it can shift from it ground state to its excited one
Only by absorbing discrete or fixed amounts of energy
That's what quantised means
 

1. What is the Hydrogen Emission Spectrum and how is it produced?

The Hydrogen Emission Spectrum is a pattern of colored lines that appear when a sample of hydrogen gas is excited by an external energy source, such as an electric current or a flame. This spectrum is produced when the electrons in the hydrogen atoms absorb energy and jump to higher energy levels, and then release that energy in the form of light as they return to their original energy level.

2. What does it mean for electrons to be "quantized"?

Electrons exist in specific energy levels around the nucleus of an atom, and they can only move between these levels by absorbing or releasing a specific amount of energy. This is known as quantization, meaning that the energy of the electrons is restricted to certain discrete values rather than being continuous.

3. How is the emission spectrum of hydrogen related to the quantized energy levels of electrons?

The different colored lines in the Hydrogen Emission Spectrum correspond to the different energy levels that the electrons can occupy. As the electrons absorb and release energy, they jump between these levels and emit light at specific wavelengths, creating the distinct lines in the spectrum. This relationship between the emission spectrum and quantized energy levels is known as the Bohr model of the atom.

4. Why is the Hydrogen Emission Spectrum important in understanding the structure of atoms?

The Hydrogen Emission Spectrum provides evidence for the quantized energy levels of electrons and the existence of discrete energy states in atoms. This is a crucial concept in understanding the structure of atoms and how they interact with each other. The emission spectrum also allows scientists to identify elements and study their properties based on the unique pattern of lines they produce.

5. How does the Hydrogen Emission Spectrum support the idea of electrons having wave-like properties?

The Hydrogen Emission Spectrum is a result of the electrons in hydrogen atoms having wave-like properties, as proposed by the wave-particle duality theory. The specific wavelengths of light emitted by the electrons correspond to their specific energy levels, which can only be explained by considering the wave-like nature of electrons and their orbits around the nucleus.

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