Infinite square well perturbation

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Homework Help Overview

The discussion revolves around a quantum mechanics problem involving a particle in an infinite square well subjected to a perturbation. The participants are exploring the implications of first-order perturbation theory on the energy levels and wave functions of the system.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the calculation of energy shifts due to the perturbation and the correction of wave functions. There is an exploration of integral calculations related to the perturbation and the conditions under which certain terms are non-zero.

Discussion Status

The conversation is ongoing, with some participants questioning the correctness of previous calculations and suggesting different approaches to the integral. There is a mix of agreement and disagreement on the methods being used, and participants are actively seeking clarification on specific aspects of the problem.

Contextual Notes

Participants are working under the constraints of first-order perturbation theory and are considering the implications of the perturbation on the wave functions and energy levels. There is a focus on the mathematical details of the integrals involved, and assumptions about the relationships between quantum numbers are being scrutinized.

kreil
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Homework Statement


A particle of mass m in the infinite square well is subjected to the perturbation H'=Vo, 0<x<L/2, H'=0 else.

(a) use first order perturbation theory to calculate the energies of the particle

(b) what are the first order corrected wave functions?

(c) if the particle is an electron, how do the frequencies emitted by the perturbed system compare with those of the unperturbed system?

Homework Equations



[tex]E_n^{(1)}=H'_{nn}=<E_n^{(0)}|H'|E_n^{(0)}>[/tex]

[tex]|E_n^{(1)}> = \sum_{m \notequal n} \frac{H_{mn}^'}{E_n^{(0)}-E_m^{(0)}} |E_m^{(0)}>[/tex]

The Attempt at a Solution


I solved part (a) and got an answer of Vo/2..i.e. each energy level is shifted up by this amount.

For part (b), I got that there is no correction to the wavefunctions, since m cannot equal n and

[tex]H'_{mn}=\frac{2V_0}{L} \int_0^{L/2} sin(\frac{n \pi}{L}x)sin(\frac{m \pi}{L}x) dx = \frac{V_0}{2} \delta_{mn}[/tex]

did I do part (b) correctly?

also, part (c) is confusing me..does anyone have any thoughts?
 
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I believe you did part (b) wrong. You might want to double check your integral. For example, if n=1 and m=2 you get [itex]4V/3\pi[/itex]. As long as one of them is even and the other odd, you will get a solution that is nonzero.
 
oo yes you're absolutely correct, the late hour affected my thinking.

since m can be any integer not equal to n, am i allowed to just set m=n+1? that would certainly help in calculating the denominator (and I don't see how else the denominator can be calculated unless m is defined in terms of n...)
 
No, because you can also have n=1 and m=4, which violates your m=n+1 rule you made up. If you know n is even, then you are just taking a sum of all odd numbers. If n is odd, then you are taking a sum of all even numbers.
 
so how am I to explicitly calculate the integral?
 
wolfram alpha gave me the following

[tex]\int_0^{L/2} sin(\frac{m \pi x}{L}) sin(\frac{n \pi x}{L}) dx = \frac{L}{2 \pi} \left( \frac{sin(\frac{\pi}{2}(m-n))}{(m-n)} - \frac{sin(\frac{\pi}{2}(m+n))}{(m+n)} \right)[/tex]
 
Use the trig identity [itex]\sin A \sin B = [\cos(A-B)-\cos(A+B)]/2[/itex].
 
Also, just solve for n=odd and n=even separately.
 

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