Internal energy of any ideal gas

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SUMMARY

The internal energy of any ideal gas is determined solely by its temperature, as established through the kinetic energy of its molecules. For monoatomic ideal gases, this energy is purely translational, while multiatomic gases include additional rotational and vibrational kinetic energies, leading to different constants in the energy equation. The relationship is expressed as $$U=n C_{V,m}T$$, where ##C_{V,m}=\frac f2 R##, with ##f## representing the degrees of freedom (3 for monoatomic and 5 for diatomic gases). This principle holds true for real gases, although the calculations become more complex.

PREREQUISITES
  • Understanding of Boltzmann Maxwell distribution
  • Knowledge of kinetic energy concepts in thermodynamics
  • Familiarity with the ideal gas law
  • Basic grasp of degrees of freedom in molecular physics
NEXT STEPS
  • Study the derivation of the Boltzmann Maxwell distribution
  • Explore the concept of degrees of freedom in multiatomic gases
  • Learn about the heat capacity of real gases and its implications
  • Investigate the differences between ideal and real gas behaviors
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This discussion is beneficial for physicists, chemists, and students studying thermodynamics, particularly those focusing on the properties of gases and their energy dynamics.

Pushoam
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The internal energy of monoatomic ideal gas is due to the kinetic energy of the molecules.
Using Boltzmann Maxwell distribution, it is calculated that the kinetic energy due to translational motion of gas molecules of an ideal gas depends only on the temperature.
In case of monoatomic gas, since the molecules can have only transational motion, the internal energy depends only on the temperature.

But, it is said that the internal energy of any ideal gas depends upon only on the temperature. Is it an approximation?
 
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Multiatomic gasses also have rotational kinetic energy and vibrational energy.
That is, they have more degrees of freedom.
Otherwise the same things apply.
It means that the internal energy indeed depends only on temperature - just with a different constant.
$$U=n C_{V,m}T$$
where ##n## is the number of moles, ##C_{V,m}=\frac f2 R## is the molar heat capacity, and ##f## is the number of degrees of freedom (f=3 for monatomic ideal gasses, f=5 for diatomic ideal gasses).
For real gasses it's of course a little more complicated.
See for instance Heat Capacity on wiki.
 
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Thank you.
 

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