Investigating the Smell of Strontium Chloride

  • Thread starter Thread starter mrjeffy321
  • Start date Start date
  • Tags Tags
    Smell
AI Thread Summary
The discussion centers on the preparation of Strontium Chloride by reacting Strontium Carbonate with dilute Hydrochloric acid. During the reaction, a fizzling sound was noted, indicating the release of Carbon Dioxide, similar to the reaction of vinegar with baking soda. An unexpected sulfur-like odor, reminiscent of rotten eggs, was detected, raising questions about its source. Participants suggest that the odor could be due to sulfur impurities in the Strontium Carbonate, referencing a specific supplier that lists sulfur as a possible contaminant. The presence of even trace amounts of hydrogen sulfide (H2S) can produce a noticeable smell, leading to the conclusion that impurities in the Strontium source are likely responsible for the sulfurous odor observed during the reaction.
mrjeffy321
Science Advisor
Messages
876
Reaction score
1
I was preparing a solution of Strontium Chloride by reacting Strontium Carbonate powder with some dilute Hydrochloric acid.
As expected, the acid reacted with the SrCO3 and began to fizzle (Carbon Dioxide forming in a similar reaction to vinegar and baking soda). I began to detect a slight odor in the air and, upon further inspection, it was coming from the SrCO3 + HCl reaction taking place. I wafted it a bit, it smelled a little like it had some Sulfur in it and it had the “rotten egg” smell. The only gas/gasses being produced in the reaction was/were colorless.

What could have caused this Sulfury odor? Does it have something to do with the Strontium? Or perhaps is it an impurity in the SrCO3?
 
Chemistry news on Phys.org
I think you probably have a sulfur impurity. This seller, http://www.atomixinc.com/strontiumcarbonate.htm , lists sulfur as a possible impurity. I get a strong sulfur smell when I add acids to iron sources because of sulfur impurities. You only need a little bit of H2S in order to smell it- 0.0047 ppm is the threshold for smelling it.
 
Last edited by a moderator:
Thats what I thought, its probably impurities.
It sure was strange getting that odor from a Strontium compound.
 
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!

Similar threads

Back
Top