Irreversible reaction in a battery

AI Thread Summary
In an ideal battery, the oxidation-reduction reaction is reversible and occurs at equilibrium, meaning the forward and reverse reactions happen at the same rate. However, in real batteries, resistivity and other factors lead to irreversible reactions. The discussion raises the question of whether, during these irreversible reactions, the chemical processes still occur in both directions but at different rates due to resistivity, or if they behave more like a one-way combustion reaction. There is also a clarification on the distinction between "reversible" and "at equilibrium," emphasizing that they are not synonymous, which is important for understanding battery chemistry.
tonyjk
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Hello,

Inside an ideal battery, the chemical reaction is reversible (at equilibrium), thus the oxydation-reduction reaction Zn + Cu2+ = Zn2+ + Cu is happening in both ways at the same rate right?

Now, for a real battery, there's resistivity inside it due to many factors, thus the chemical reaction is irreversible. My question is, during the irreversible reaction, is the reaction happening in both ways but at different rate due to resistivity inside the battery or it is just like the combustion reaction happening in one way?

Thanks
 
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Please elaborate. "Reversible" and "at equilibrium" are two different things, I don't see why you are mixing them.
 
Borek said:
Please elaborate. "Reversible" and "at equilibrium" are two different things, I don't see why you are mixing them.
Sorry but chemistry is not my domain. I thought that a chemical reaction at equilibrium thus it is a reversible reaction.
 
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