Is Ferric Oxide Protective or Not?

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The discussion centers on the contradictory roles of ferric oxide (Fe2O3) in corrosion processes. In some conditions, such as exposure to strong oxidizing agents like concentrated nitric acid, Fe2O3 forms a protective layer that passivates iron, preventing further corrosion. Conversely, in the presence of oxygen, water, and hydrogen ions, Fe2O3 does not provide protection and allows rusting to continue. The protective properties of Fe2O3 appear to vary significantly depending on environmental conditions. Understanding these differences is crucial for applications involving iron and its corrosion resistance.
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Homework Statement


There are two lines in my textbook :
" Iron is passivated by strong oxidising agents like conc.##HNO_3,K_2Cr_2O_7## due to the formation of a protective coat of ##Fe_2O_3##."
And the other line says:
"Rusting occurs in the presence of ##O_2,H_2O## and ##H^+## resulting in the formation of ##Fe_2O_3## which is not protective and the corrosion continues"
Whats this? One line says that ##Fe_2O_3## is protective and other says it is not !

Homework Equations

The Attempt at a Solution


Can it be the reason that protective property of ##Fe_2O_3## is different for different conditions?
 
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mooncrater said:
Can it be the reason that protective property of ##Fe_2O_3## is different for different conditions?

Apparently. Concentrated nitric acid is safely transported in steel tanks, as the iron from these tanks gets passivated and doesn't dissolve in the acid. Same steel will rust if put in sea water.
 
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