Is My Solution for Proving E = 0 and E < 0 Invalid?

[Void123]

Homework Statement

I have an infinite square well and I am asked to show why E = 0 and E < 0 does not satisfy the Schrodinger's equation. I must do this by applying the boundary conditions.

For E = 0:

I argued that the second derivative of the wave function is zero.

So,

\Psi(x) = A + Bx

By imposing the boundary conditions \Psi (0) = \Psi (a) = 0 I get:

\Psi(x) = Bx

and

\Psi (a) = Ba = 0

Therefore I concluded that:

(1) B cannot be zero, or else we get \Psi(x) = 0 which is physically unacceptable
(2) a\neq0 since a is the upper bound.

Perhaps before presenting my second solution to E < 0 I should make sure all the above is correct.

Is it valid?

Homework Equations

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The Attempt at a Solution

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[Redbelly98]

Looks good so far.

 

[Void123]

E < 0:

The second derivative of the wave function I set equal to k^{2}\Psi(x)

The solution is \Psi(x) = Ae^{-kx} + Be^{kx}, where the first term on the right cancels since it blows up at infinitely large values of x.

Thus, \Psi(0) = Be^{k0} = 0 (after imposing the boundary conditions), which does not give us a satisfying solution for B or e^{0}. Neither does it work for \Psi(a) = 0.

So, the boundary conditions don't work.

 

[Redbelly98]

Note that the solution and coefficients A and B are only valid within 0<x<a. So it is okay if this Ψ(x) expression blows up at infinity, since the actual Ψ(x) will be a different expression for x<0 or x>a.

Use both boundary conditions (at x=0 and a), and the expression you wrote for Ψ(x).