[itex]\epsilon_r[/itex] (relative permittivity) is usually frequency-dependent, to a greater or lesser degree. A favourite example is water, whose [itex]\epsilon_r[/itex] at very low frequencies is about 80, but at optical frequencies (around [itex]5 \times 10^{14}[/itex] Hz, is about 1.8. This is because water molecules are strongly polarised, and at low frequencies can align themselves strongly with the electric field. At high frequencies they can't flail about (librate?) fast enough to keep pace with the changing field. Except for ferromagnetic materials, [itex]\mu_r[/itex] (relative permeability) is pretty much 1 at all frequencies.