I assume you are talking about a purely static situation.
Without external electric field, the net electric charge in each point of the conductor is zero (lets keep it simple: I assume there are no excess charges in the conductor).
Under the action of an external field, the positive and negative charges in the conductor displaces, so that the net electric charge in each point of the conductor (local charge) is not zero. If you sum the charge of all these points over the whole volume (global charge), it will however remains equal to zero.
The local charges are so smart that they arrange themselves so that the field is zero in the whole conductor. It is however a very difficult task to compute the local distribution for complex geometries.