Is the Radial Wave Function R_{31} Normalized Correctly?

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Homework Help Overview

The discussion revolves around the normalization of the radial wave function R_{31} in quantum mechanics, specifically focusing on the integration process to verify that the function satisfies the normalization condition.

Discussion Character

  • Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants explore the integration of the radial function and question whether all necessary factors, such as the coordinate system and constants, have been correctly accounted for in the normalization integral.

Discussion Status

Some participants have provided insights into the integration process and pointed out potential errors in the original poster's approach, while others have referenced useful integrals related to the problem. The discussion is ongoing, with multiple interpretations being explored.

Contextual Notes

Participants are working within the framework of spherical coordinates and are addressing the implications of this choice on the normalization integral. There is an emphasis on ensuring that all terms are correctly included in the calculations.

atarr3
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Homework Statement


Show that the radial function R_{31} is normalized.

Homework Equations


\frac{1}{a_{0}^{3/2}}\frac{4}{81\sqrt{6}}\left(6-\frac{r}{a_{0}}\right)\frac{r}{a_{0}}e^{-r/3a_{0}}

\int^{\infty}_{0}r^{2}R_{31}*R_{31}dr=1

The Attempt at a Solution


So I plugged that radial function in and got \int^{\infty}_{0}a_{0}^{2}u^{2}\left(6u-u^{2}\right)^{2}e^{-2u/3}du=1 all multiplied by some constant and u=\frac{r}{a_{0}}

I'm getting \frac{243}{4} times the constant, and that does not equal one. So I feel like I'm not using the right equation for this one.
 
Last edited:
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Remember what coordinate system you are working in.
 
Spherical coordinates. So there's an r^2 thrown in there. Did I not account for everything in my integral?
 
Well, it looks like you didn't in your equation with the u's.
 
I'm seeing an extra a_o^2, since there's an (\frac{1}{a_0^{3/2}})^2 = \frac{1}{a_0^3} term, an r^2 = a_0^2u^2 term, and a dr = a_0 du term:

\frac{1}{a_0^3}a_0^2u^2a_0 du = u^2 du

I'm curious as to how you're going about integrating

C\int_0^\infty (u^6 - 12u^5 + 36u^4)e^{-2u/3} du ?

Does this have to be done by repeated parts (after you split it up of course), or is there a trick?
 
dotman said:
I'm curious as to how you're going about integrating

C\int_0^\infty (u^6 - 12u^5 + 36u^4)e^{-2u/3} du ?

Does this have to be done by repeated parts (after you split it up of course), or is there a trick?

A very useful definite integral that was given to me when I learned about the hydrogen atom is

\int^{\infty}_{0}x^n \; e^{-ax}dx=\frac{n!}{a^{n+1}}; \; (a>0;\; n\; integer \:>0)
 

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