Figure 2.1 seems odd; it appears to be plotting the distribution of velocity (note, velocity, not speed) versus kinetic energy. The energy distribution does not have a maximum at zero. Look up the MB distribution; observe its forms for the distribution of velocity, speed and energy.
Equation 2.1 is the distribution of vectorial velocity, i.e. with a particular direction as well as magnitude (or alternatively, a particular set of components {vx, vy, vz}). It has a maximum at zero velocity. The distribution of the speed is found by summing Eq. 2.1 over all directions (or all sets of {vx, vy, vz} that give the same magnitude v), and is given by
f(v) = 4πv2f(v)
This has a value of zero at v=0, and a maximum at a finite v. The energy distribution goes as E1/2e-E/kT