DrClaude said:
you are confusing the frequency of the quantum oscillator and that of the photon.
That is precisely what I was trying to avoid... such confusion. There is on the one hand the frequency/ies of the oscillator/s and the frequency of "what happens". That is clear.
Our disagreement is that for you the frequency of "what happens" is the frequency of the oscillator.
DrClaude said:
The transition appears at the frequency of the oscillator, not at a difference of frequencies in the oscillator.
But if you look at the details, the surprise is that it is not. Though maybe I went astray somewhere. Let me explain my reasoning.
DrClaude said:
It is best to think of it in terms of energy even when considering the photon, and only convert (if needed) to the frequency of the photon afterwards.
Yes, I can do that:
(I am thinking of the hydrogen atom and simplifying with signs, for my own sake...)
Take an oscillator located at level n = 3 with E3 = hcR
c/3
2
It suffers a "transition" down to level n = 2 with E2 = hcR
c/2
2
The E difference is = hcR
c ( 1/2
2 - 1/3
2)
But this is equal also to hf, being f the frequency of the photon.
So the f of the photon that will be emitted and detected is cR
c ( 1/2
2 - 1/3
2)
But the funny thing is that if you think in terms of frequencies, you get the same result:
Take an oscillator located at level n = 3 with frequency f3 = cR
c/3
2
It suffers a "transition" down to level n = 2 with frequency f2 = cR
c/2
2
The frequency difference f2 - f3 is = cR
c ( 1/2
2 - 1/3
2)
This is again the frequency of the photon causing the "transition".
Hence thinking in terms of frequencies does not look so wrong since it leads to a correct conclusion. And in the light of this the frequency at which the "phenomenon" appears is not the frequency of the oscillator but a frequency difference between oscillators' modes.
I can concede however that if you call such phenomenon an "oscillator transition", this sounds strange, because it is actually true (this is what I have actually learned through this thread) that you cannot excite or force an oscillator to transit to a higher frequency by applying a frequency difference, so it looks only logical to seek refuge in the idea that the influence/exciting source is oscillating at the frequency of such oscillator, thus increasing its amplitude. But if I didn't go astray above, that is not what happens in the phenomenon at hand.
Thus I turned to the mechanical realm looking for an example where a "frequency difference" was of any use. I have concluded that such thing can serve for increasing the amplitude not of an individual oscillator in a system but of the overall system. For example, in the two-pendulum case, an influence at the "beat frequency" would increase the overall amplitude of the system. Or in the complex sound wave, such influence would also enhance the amplitude difference between the beats. If you applied this construct to the QM system of an atom, you would infer that the photon does not provoke strictly speaking an electron transition but an overall increase of amplitude of the envelope (the atom) as such.
But please note: I am not at all proposing that as a theory, I am more prudent than that...! Forget the QM analog, I was just trying to understand if the above described mech systems work as I have explained before, which no one has answered so far!