What do you mean by this? Do you mean writing a vector ##v=\sum_{\iota \in I}v_\iota b_ \iota## as ##v=(..., v_\iota , ...)## in coordinate form according to a basis ##\{b_\iota\}_{\iota \in I}##?A vector is something which a matrix applies to: ##v \mapsto Av##. Of course you may take ##v## as a row or column vector of ##A## and fill up the rest with zeroes, but why? ##v## and ##A## are different objects, one is something that make up vector spaces and the other one is a mapping between vector spaces.which means ##Mv = c\, v##.So your vector ##v## (with the dimensions above) is a ##(3\times 1)-##matrix and ##M## a ##(3\times 3)-##matrix.This depends on how you "represent" ##v## by ##A##. If ##A = (v,0,0)## then of course. But why should you do this?Again. There is no meaning in "representing" a vector as a square matrix, unless in very special cases (which I can't imagine). The only natural way is to see a vector as a ##(n \times 1)-##matrix.
My personal opinion is, that you should forget about it and recapture what vectors and linear mappings are. They are not supposed to be messed up.