Non-equilibrium states in semiconductors occur when external factors, like light or UV radiation, cause electrons to gain kinetic energy and transition to higher energy levels. This process can also result from internal interactions, such as collisions between electrons. The distinction lies in the fact that these states are temporary and differ from the stable equilibrium state of electrons. Understanding these dynamics is crucial for applications in semiconductor technology. Overall, non-equilibrium states play a significant role in the behavior and functionality of semiconductors.