Oxidation reaction from alcohol to aldehyde

AI Thread Summary
Oxidation reactions of primary alcohols to aldehydes or carboxylic acids, and secondary alcohols to ketones, require protons to facilitate electron transfer during the reduction of the oxidizing agent, such as MnO4. The presence of a strong electrolytic solution is essential for this process, as it provides the necessary protons for the reaction. The oxidation of alcohols involves the loss of hydrogen atoms, but the reaction's efficiency is enhanced by maintaining a low pH environment. Protons play a critical role in the overall chemistry, ensuring that the oxidizing agent can effectively oxidize the alcohol. Understanding this mechanism is vital for grasping the underlying principles of oxidation reactions in organic chemistry.
kathyt.25
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My original question:
Why do oxidation reactions from primary alcohols to aldehydyes/carboxylic acids, or secondary alcohols to ketones require an acid (positive hydrogen ion)? I can see that the reason we have an oxidizing agent is to take away two hydrogen ions from the alcohol, but
why do we need an additional positive hydrogen ion?

Someone's response:
You need a strong electrolytic solution to facilitate the transition
(movement) of electrons... because in order for MnO4 to be reduced
(and cause an oxidation), it needs a source of protons as part of the
chemistry.


Can someone explain WHY we need protons in order for the oxidizing agent to be reduced, and therefore oxidize the alcohol?
If an alcohol is being oxidized to become an aldehyde, it's losing two hydrogen atoms, which are positive... why would these positive hydrogen atoms (protons) be drawn to the source of protons?
 
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It has nothing to do with alcohol/aldehyde. MnO4- half reaction is

MnO4- + 8H+ -> Mn2+ + 4H2O + 5e-

To be an effective oxidizer it requires low pH.
 
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