The discussion focuses on calculating the percent abundance of Br-81 in bromine, which consists of isotopes Br-79 and Br-81. The atomic mass of bromine is given as 79.9. A formula is provided to determine the percent abundance of Br-81, which involves the atomic masses of both isotopes. By substituting the values into the formula, it is concluded that the percent abundance of Br-81 is 45%. This indicates that in a sample of 100 bromine atoms, 45 are Br-81 and 55 are Br-79.