Perturbed Ground State Wavefunction with Parity

Click For Summary
SUMMARY

The discussion focuses on the perturbation of the ground state wavefunction of a particle in a Coulomb potential, specifically analyzing the implications of parity symmetry on the coefficients \(C_{nlm}\) in the perturbed state \(|\Psi_{0}\rangle\). The participants explore how the parity operator affects the allowed transitions between states, concluding that perturbations must preserve parity, thus restricting \(C_{nlm}\) to states with the same parity. The conversation also highlights the relevance of time-independent perturbation theory in understanding these relationships.

PREREQUISITES
  • Understanding of quantum mechanics, particularly perturbation theory.
  • Familiarity with the Coulomb potential and hydrogenic wavefunctions.
  • Knowledge of symmetry operations in quantum mechanics, especially parity.
  • Basic grasp of angular momentum quantum numbers (n, l, m).
NEXT STEPS
  • Study the implications of parity in quantum mechanics, focusing on selection rules.
  • Learn about time-independent perturbation theory in greater detail.
  • Explore the role of symmetry in quantum systems, including rotational and time-reversal symmetries.
  • Review examples of perturbation theory applications in quantum mechanics, particularly in atomic systems.
USEFUL FOR

Students and professionals in quantum mechanics, particularly those studying atomic physics, quantum perturbation theory, and symmetry operations. This discussion is beneficial for anyone preparing for exams or seeking to deepen their understanding of wavefunction perturbations.

logic smogic
Messages
54
Reaction score
0
[SOLVED] Perturbed Ground State Wavefunction with Parity

Homework Statement


A particle is in a Coulomb potential

H_{0}=\frac{|p|^{2}}{2m} - \frac{e^{2}}{|r|}

When a perturbation V (which does not involve spin) is added, the ground state of H_{0} + V may be written

|\Psi_{0}\rangle = |n=0,l=0,m=0\rangle + \sum C_{nlm}|n,l,m \rangle

where |n,l,m\rangle is a Hyrdogenic wavefunction with radial quantum number n and angular momentum quantum numbers l, m.

Consider the following possible symmetries of the perturbation V. What constraints, if any, would the presence of such a symmetry place on the possible values of the coefficients C_{nlm}?

(i) Symmetry under Parity.
(ii) Rotational symmetry about the z axis.
(iii) Full rotational symmetry.
(iv) Time reversal symmetry.

The Attempt at a Solution



Let's stick to just part (i) for now.

Initially, I want to understand what the question is asking, and what that formula for the ground state ket means. Here's what went through my head:

1. Time-Independent perturbation theory tells us that the eigenkets can be written:

|n \rangle = |n_{0} \rangle + \sum |m_{0} \rangle \langle m_{0} | n \rangle

where,

\langle m_{0} | n \rangle = \lambda \frac{\langle m_{0} | V | n \rangle}{E_{n} - E_{m,0}}

2. Comparing this to the equation of the perturbed ground state (in the statement of the problem), it looks like,

|n=0,l=0,m=0\rangle \rightarrow |n_{0} \rangle

and,

|n,l,m \rangle \rightarrow |m_{0} \rangle

which leaves the "coefficients" as,

C_{nlm} \rightarrow \langle m_{0} | n \rangle

3. As for parity, I know that if \pi is the parity operator, then for an operator A,

\pi^{\dagger} A \pi = \pm A

Presumably, I should apply this to V, and learn something about the possible values of the coefficients.

This is where I'm stuck. I've no idea how this is supposed to restrict the values that C_{nlm} can take. Any suggestions or hints in the right direction?
 
Last edited:
Physics news on Phys.org
Any thoughts on this? The basic question here is:

How does parity create selection rules?

Perhaps someone could just lay out it for me, or point me to a nice tutorial. My book doesn't provide an example or anything of that sort, and I have an exam today! Thanks much.
 
Something's not kosher here...

So the strangest thing just happened. I just had a Quantum Mechanics exam today. I came home and decided to research a couple of the problems on the exam, and sure enough, on your thread are posted 2 of the EXACT questions that were on my exam. But even stranger than this, is the fact that these posts were made 2 days before my test...I wonder how that happened?? Any suggestions anyone?

-What school did you say that you attended by the way?
 
logic smogic said:

Homework Statement


A particle is in a Coulomb potential

H_{0}=\frac{|p|^{2}}{2m} - \frac{e^{2}}{|r|}

When a perturbation V (which does not involve spin) is added, the ground state of H_{0} + V may be written

|\Psi_{0}\rangle = |n=0,l=0,m=0\rangle + \sum C_{nlm}|n,l,m \rangle

where |n,l,m\rangle is a Hyrdogenic wavefunction with radial quantum number n and angular momentum quantum numbers l, m.

Consider the following possible symmetries of the perturbation V. What constraints, if any, would the presence of such a symmetry place on the possible values of the coefficients C_{nlm}?

(i) Symmetry under Parity.
(ii) Rotational symmetry about the z axis.
(iii) Full rotational symmetry.
(iv) Time reversal symmetry.


The Attempt at a Solution



Let's stick to just part (i) for now.

Initially, I want to understand what the question is asking, and what that formula for the ground state ket means. Here's what went through my head:

1. Time-Independent perturbation theory tells us that the eigenkets can be written:

|n \rangle = |n_{0} \rangle + \sum |m_{0} \rangle \langle m_{0} | n \rangle

where,

\langle m_{0} | n \rangle = \lambda \frac{\langle m_{0} | V | n \rangle}{E_{n} - E_{m,0}}
This is a very bad choice of notation because \langle m_{0} | n \rangle has already a clear meaning. Maybe V_{m_0,n} or something similar would be better.
2. Comparing this to the equation of the perturbed ground state (in the statement of the problem), it looks like,

|n=0,l=0,m=0\rangle \rightarrow |n_{0} \rangle

and,

|n,l,m \rangle \rightarrow |m_{0} \rangle

which leaves the "coefficients" as,

C_{nlm} \rightarrow \langle m_{0} | n \rangle

3. As for parity, I know that if \pi is the parity operator, then for an operator A,

\pi^{\dagger} A \pi = \pm A

Presumably, I should apply this to V, and learn something about the possible values of the coefficients.

This is where I'm stuck. I've no idea how this is supposed to restrict the values that C_{nlm} can take. Any suggestions or hints in the right direction?

V cannot change the parity therefore the two states connected by V must have the same parity. What is the parity of a state with quantum numbers l,m ?
 

Similar threads

  • · Replies 0 ·
Replies
0
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
0
Views
1K
Replies
1
Views
2K
  • · Replies 13 ·
Replies
13
Views
3K
  • · Replies 1 ·
Replies
1
Views
3K
Replies
0
Views
2K
Replies
10
Views
2K
Replies
3
Views
2K
  • · Replies 0 ·
Replies
0
Views
2K