To calculate the % hydrolysis of 1 M Na2CO3 with [OH-] at 5.4x10^(-4), the relevant hydrolysis reactions involve the carbonate ion (CO3^(2-)) reacting with water to form bicarbonate (HCO3^(-1)) and hydroxide ions (OH^-). The equilibrium constants for the reactions are derived from the dissociation constants (Ka) of carbonic acid (H2CO3), specifically Ka1 and Ka2. Using the given [OH-], one can determine the concentrations of HCO3^(-1) and CO3^(2-) to find the % hydrolysis. The discussion also touches on the definition of hydrolysis percentage and emphasizes the importance of showing effort in problem-solving. Understanding these concepts is crucial for accurately calculating the % hydrolysis.