Preferred Crystal Structure of Steel (BCC vs FCC)

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The different microstructures of steel at varying temperatures are primarily influenced by the crystal structures of iron, which transition from body-centered cubic (BCC) in ferrite at lower temperatures to face-centered cubic (FCC) in austenite at higher temperatures. The addition of carbon alters the iron lattice, creating solid solutions that enhance properties like strength and ductility. Temperature affects atomic mobility and the energy of the system, favoring the FCC structure in austenite due to its ability to accommodate more carbon and other alloying elements. The iron-carbon equilibrium diagram illustrates these transformations and their relationship with temperature and carbon content. Understanding these principles is crucial for manipulating steel properties for various applications.
Brian Yao
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What are the reasons behind the different microstructures of steel at different temperatures? I don't understand why steel at high temperatures (austenite phase) would favor an FCC crystal structure while steel at lower temperature (ferrite) would favor a BCC crystal structure.
 
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Brian Yao said:
What are the reasons behind the different microstructures of steel at different temperatures? I don't understand why steel at high temperatures (austenite phase) would favor an FCC crystal structure while steel at lower temperature (ferrite) would favor a BCC crystal structure.

carbon in small quantities is added to iron and one can get steel.
the size of carbon atoms is less than the spacing between iron atoms so it goes in and forms a solid solution-thus deforming the structure of iron.
The iron-carbon equilibrium diagram (phase diagram) is a plot of transformation of iron with respect to carbon content and temperature.
this admixture of carbon leads to several changes in its properties -stress bearing and ductileness etc.
If one observes the metallurgy of steel in detail related to its various phases your question can be handled-
its better you see a site which handles your querry...

ref; <http://nptel.ac.in/courses/105106112/1_introduction/2_metallurgy_of_steel.pdf>
 
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drvrm said:
carbon in small quantities is added to iron and one can get steel.
the size of carbon atoms is less than the spacing between iron atoms so it goes in and forms a solid solution-thus deforming the structure of iron.
The iron-carbon equilibrium diagram (phase diagram) is a plot of transformation of iron with respect to carbon content and temperature.
this admixture of carbon leads to several changes in its properties -stress bearing and ductileness etc.
If one observes the metallurgy of steel in detail related to its various phases your question can be handled-
its better you see a site which handles your querry...

ref; <http://nptel.ac.in/courses/105106112/1_introduction/2_metallurgy_of_steel.pdf>
Okay I understand that carbon in Fe strengthens the metal by creating distortions within the lattice but I don't understand how temperature plays a role in determining the preferred crystal structure.
 
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