Proving direct band gap property of a semiconductor

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SUMMARY

The discussion focuses on proving the direct band gap property of Transition Metal Dichalcogenides (TMDs) through experimental methods. The user suggests using Photoluminescence (PL) measurements for optical band gap verification and mentions the limitations of Angle-Resolved Photoemission Spectroscopy (ARPES) due to the small channel length of approximately 5 µm. Additionally, Band Edge Absorption Spectroscopy is proposed as an alternative method, highlighting its effectiveness in demonstrating sharper absorption curves characteristic of direct band gap semiconductors.

PREREQUISITES
  • Understanding of Photoluminescence (PL) measurements
  • Familiarity with Band Edge Absorption Spectroscopy techniques
  • Knowledge of Transition Metal Dichalcogenides (TMDs)
  • Experience with the scotch tape method for material exfoliation
NEXT STEPS
  • Research advanced techniques for measuring band gap properties in TMDs
  • Explore the principles and applications of Band Edge Absorption Spectroscopy
  • Investigate alternative methods to ARPES for small-scale samples
  • Learn about the implications of direct vs. indirect band gap semiconductors in applications
USEFUL FOR

Researchers, material scientists, and experimental physicists focused on semiconductor properties, particularly those working with Transition Metal Dichalcogenides and optical measurement techniques.

hasniali
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Hi,
How can I prove direct band gap property of a Transition Metal Dichalcogenide electrically and optically through experimentation? I can use PL measurements to prove this for optical band gap. Is there any other equipment or technique to prove this? I can not use ARPES because channel length is around 5 um. I think ARPES requires larger films. I am using scotch tape method for exfoliation. Any help in this regard is highly appreciated. Thank you.
 
Another way is Band edge absorption spectroscopy. Absorption curve is much sharper for direct band semiconductors.
See this:

https://www.researchgate.net/post/How_can_you_know_the_material_is_of_direct_band_gap_or_indirect_bandgap
 
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