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Quantum Physics - Fine Structure

  1. May 11, 2009 #1
    1. The problem statement, all variables and given/known data
    Estimate the size of the fi ne structure of the 2p con guration in hydrogen-like
    sodium (i.e. sodium ions with all but the last electron removed). Why can't we use
    perturbation theory to calculate the e ffect of the spin-orbit interaction in hydrogen-like uranium?


    2. Relevant equations



    3. The attempt at a solution
    I don't understand what the question means! Is it looking for a literal size of some sort, or does it want the size of the energy change from the energy of a Gross Structure state to a petrubed state?

    How would you read this question?

    Thanks
     
  2. jcsd
  3. May 11, 2009 #2
    For sodium you have Z=11. So you can use the same math for the hydrogen atom except replace Z with 11.

    Also, perturbation theory only works for very small terms. Once the energies in perturbation theory start getting to the same scale as the initial energies, then it doesn't apply. And look at uranium, it has Z=92. Since the fine structure constant is on the order of Z^2, you get a factor of Z^2 = 8464 which isn't small anymore.
     
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