Moving up the mass scale, first neutrons (each nearly 2,000 times the mass of an electron) and then beams of atoms and molecules were shown to diffract like waves when passed through small apertures. Over the past ten years or so, the wave-particle duality has been demonstrated ever more clearly. Not just diffraction (in which one beam, or wave, bends as it passes an obstruction) but interference (in which two beams or waves interact with one another) has been demonstrated both for electrons and atoms. Now, a team of researchers at the University of Paris-North, at Villetaneuse in France, has done the trick with molecules.
In the traditional version of the interference experiment with light, two beams of light are generated by passing light from a single source through two slits in a screen. Then, the two beams are allowed to interfere, producing a characteristic stripey pattern of light and shade. The new experiment is conceptually similar, but instead of passing through holes in a screen the iodine molecules (I2, which each have a mass about 254 times that of a neutron) interact with laser beams. The first interaction, with a pair of laser beams, puts each molecule into what is known as a "superposition of states", effectively two wave packets marching side by side. A second pair of laser beams recombines the wave packets to make "particles". At least, that is the theory. What happens in practice? After they have passed through the laser beams, the iodine molecules arrive at a detector. The distribution of the molecules arriving at the detector does not resemble the pattern you would expect if they were a stream of particles traveling through the experiment, but exactly matches the stripey pattern of peaks and troughs corresponding to interference by waves (Physics Letters A, vol 188 p 187). These are the heaviest "particles" which have ever demonstrated their wave "character" directly in experiments.