Question about entropy of photons

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    Entropy Photons
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Discussion Overview

The discussion centers on the entropy of photons, particularly in the context of blackbody radiation and the implications of volume changes on photon behavior. Participants explore theoretical aspects, definitions, and statistical mechanics related to photon entropy, temperature, and the nature of blackbody radiation.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • Some participants argue that each photon has an entropy of one, independent of energy or volume, while others challenge this notion by discussing the relationship between entropy, temperature, and volume.
  • One participant introduces the concept of Bose-Einstein statistics and suggests that the entropy of a system of photons is not constant and can be calculated using the partition function.
  • Another participant asserts that temperature, pressure, internal energy, and entropy are not applicable to a single photon, as these quantities are defined for macroscopic systems.
  • There is a discussion about the number of possible spin states of photons, with some asserting that photons have only two degrees of freedom, while others mention three possible spin states.
  • Participants debate whether increasing the volume of a box filled with blackbody radiation affects the number of photons, with one questioning the implications of particle number conservation in quantum field theories.
  • One participant suggests that the average number of photons can be derived from energy considerations without needing quantum electrodynamics, referencing the Stefan-Boltzmann law.

Areas of Agreement / Disagreement

Participants express multiple competing views regarding the entropy of photons, the applicability of thermodynamic quantities to single photons, and the effects of volume changes on photon number. The discussion remains unresolved with no consensus reached.

Contextual Notes

Limitations include the dependence on definitions of entropy and temperature, the complexity of photon statistics, and the unresolved nature of how changes in volume affect photon behavior in blackbody radiation.

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  • #32
dextercioby said:
I made the calculation explicitely here:

https://www.physicsforums.com/showthread.php?t=58208&page=1

Daniel.
Your answer was:
[tex]\langle N\rangle=\frac{2k^{3}\zeta(3)}{\pi^{2}c^{3}\hbar^{ 3}} VT^{3}[/tex]

And my answer was:
[tex](16 \pi Zeta[3] k^3 V T^3 ) / (c^3 h^3)[/tex]

So, taking into account that [tex]\hbar = h / 2\pi[/tex], it looks like we got the same answer.
 
  • #33
JesseM said:
I tried doing this integral and I didn't get the answer you give above

whoops.. there was supposed to be a proportionality symbol there, showing that N was proportional to VT^3, but apparently I got the wrong TeX command for that.

JesseM said:
Well, see the second paragraph of my last post above, I don't think an infinite average fluctuation size necessarily means the average itself is physically meaningless. If it was meaningless, why would your textbook give it at all? Does it make any comments about the significance of the infinite average fluctuation result?

So I was actually basically quoting the textbook. The author shows that formula, then says that it can't really be taken at facevalue as he calls attention to the fact that the fluctuations are infinite. Unfortunately, he doesn't elaborate beyond that.

JesseM said:
Also, I was thinking about what it means to say the average size of fluctuations is infinite, and it seems to me it doesn't automatically mean that talking about the average is physically meaningless. For example, imagine a situation where there's a 1/2 chance the fluctuation will deviate from the average by 2, a 1/4 chance it will deviate from the average by 4, a 1/8 chance it will deviate from the average by 8, etc...in this case the average fluctuation would be 2*(1/2) + 4*(1/4) + 8*(1/8) + ... = 1 + 1 + 1 + ... = infinite, but it's still true that in 3/4 of all cases you'll get within 4 of the average. Now, I'm not suggesting the typical fluctuations in photon number would really be so small, but the point is that in principle an infinite average fluctuation size in the value of a quantity doesn't mean that it's meaningless to talk about the average value of that quantity.

hmm.. I see what you are saying.. in your example though, you are considering deviations in only one direction... fluctuations about the average should happen in both positive and negative directions, so the average fluctuation should be zero. The formula I posted was for mean square fluctuation, which in this example would be 4*(1/2) + 16*(1/4) + 64*(1/8) + ... = infinity much faster :) So in 3/4 of the cases this comes out to be 6.. not much different, but also look that the formula is divided by the average number of particles squared.. so the rms deviation is root six or about 2.5 times the number of particles in the system, by this technique, 3/4 of the time. So I think it's not only the fact that the mean square deviation is infinite, but that even divided by N^2 (a very large number) it is still infinite, so it seems to me that indicates it diverges very quickly. But I don't have any analysis to back that up, yet.
 

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