Electromagnetic (EM) waves in a charge-free homogeneous medium have electric (E) and magnetic (B) fields that are perpendicular to the direction of propagation. However, in specific scenarios such as waveguides, near-field regions of antennas, and on the surface of conductors, E and B can exhibit different alignments relative to the propagation direction. In waveguides, while E and B remain mutually perpendicular, one may have an axial component, deviating from being perpendicular to the propagation direction. Near-field interactions and evanescent waves can lead to complex field arrangements where E and B are not strictly perpendicular. The discussion also touches on the implications of static fields and Poynting flux in the presence of a magnet and charged sphere.