Radial probability distribution (rpd)

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Discussion Overview

The discussion revolves around the concept of radial probability distribution (rpd) in quantum mechanics, specifically focusing on the relationship between the radial wavefunction and the volume of a spherical shell. Participants explore the mathematical formulation and implications of these concepts.

Discussion Character

  • Technical explanation, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant states that the radial probability density is defined as the square of the radial wavefunction multiplied by the volume of the spherical shell, questioning the cancellation of the differential element dr in the expression.
  • Another participant asserts that the density function is the derivative of the distribution, suggesting this is where the dr is accounted for.
  • A subsequent reply seeks clarification on the derivative, asking with respect to what variable it is taken.
  • Another participant responds by indicating that the cumulative distribution function F(r) is related to the density function R(r) through the derivative dF(r)/dr.

Areas of Agreement / Disagreement

Participants express uncertainty regarding the treatment of the differential element dr and the relationship between the radial probability density and the cumulative distribution function. No consensus is reached on these points.

Contextual Notes

The discussion highlights potential limitations in understanding the definitions and relationships between the radial wavefunction, radial probability density, and cumulative distribution, as well as the role of the differential element in these expressions.

brainyman89
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Radial Probability Density = R(r) : Square of the Radial Wavefunction
The required volume is determined by the volume of the SPHERICAL SHELL enclosed between a sphere of radius (r+dr) and a sphere of radius r

rpd = radial probability density × volume of the spherical shell = R2 × 4πr2 drhow then did they cancel the dr and directly write:
rpd = R2 × 4πr2

??

also how could only radial probability be multiplied by volume? shouldn't the whole wave function be multiplied by the volume?
 
Last edited:
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The density function is the derivative of the distribution - that's where the dr went.
 
mathman said:
The density function is the derivative of the distribution - that's where the dr went.

derivative with respect to what?
 
brainyman89 said:
derivative with respect to what?

The cumulative distribution is F(r) and the density function R(r) = dF(r)/dr
 

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